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Alexey gromov forex reviews

Опубликовано в Mechanical forex strategies | Октябрь 2, 2012

alexey gromov forex reviews

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A service member of pro-Russian troops stands at a former fighting position of the Ukrainian armed forces outside the town of Svitlodarsk in the Donetsk region. Two captured Russian soldiers pleaded guilty on Thursday to shelling a town in eastern Ukraine in the second war crimes trial of the conflict.

At the trial in the Kotelevska district court in central Ukraine, state prosecutors asked for Alexander Bobikin and Alexander Ivanov to be jailed for 12 years for violating the laws of war. A defense lawyer asked for leniency, saying the two soldiers had been following orders and repented.

Bobikin and Ivanov, who stood in a reinforced glass box, acknowledged being part of an artillery unit that fired at targets in the Kharkiv region from the Belgorod region in Russia. The shelling destroyed an educational establishment in the town of Derhachi, prosecutors said.

The servicemen, described as an artillery driver and a gunner, were captured after crossing the border and continuing the shelling, the prosecutor general's office said. We fired at Ukraine from Russia," Bobikin told the court in proceedings that were streamed live. Asking not to be handed the maximum jail term, Ivanov said: "I repent and ask for a reduction in the sentence. Russia is not going to cut itself off from the global economic arena despite the attempts of forces trying to force it out, President Vladimir Putin said during his address at the Eurasian Economic Forum in Bishkek, Kyrgyzstan on Thursday.

Joining the event virtually, Putin said the exit of some foreign companies from the Russian market over Russia's special military operation in Ukraine might be for the best. Russia does not accept Western accusations of blocking grain exports from Ukraine, instead saying that the actions of these countries led to such a "blockade," Kremlin spokesperson Dmitry Peskov said on Thursday, TASS reported. Russia is waiting for Ukraine to accept its demands and realize the real situation, Peskov said.

Tehran has offered to host Russian and Ukrainian delegations for talks, according to statements by the Iranian foreign ministry on Thursday. Putin "underestimated" the "resolve and strength" of allies in countering his "aggression" in Ukraine, said Scholz at the World Economic Forum in Davos, noting that Moscow has also now pushed Finland and Sweden to join the NATO defense alliance.

Negotiations are ongoing about a possible corridor for Ukraine grain exports via Turkey, Reuters reported on Thursday, citing a senior Turkish official. The international community should help create a "safe passage" to enable the millions of tonnes of grain stuck in Ukraine to leave the country, Ukrainian deputy Prime Mnister, Yuliia Svyrydenko, told the BBC earlier, saying that some sort of "corridor" was needed. He said all Ukrainian fighters hiding out at Azovstal will be found, as some may still be in there "hiding or lagging behind when surrendering.

On May 17, Ukraine's military command said the mission to defend the besieged Azovstal steel plant in Mariupol was over and pledged to rescue servicemen still trapped inside. Later in the week, Russian forces claimed the "complete liberation" of the Azovstal steel plant and Mariupol as a whole. Fighting between Russian and Ukrainian forces has reached the outer limits of the key eastern Ukrainian city of Severodonetsk, the governor of Luhansk said Wednesday, describing combat as "very difficult.

Widow and daughter of Andriy Vertiev, a Ukrainian serviceman, at his funeral in Lviv. Of these frozen assets, only less than one-tenth is in the EU, according to information that the European Commission has collected from the 27 EU governments, EU Justice Commissioner Didier Reynders told a news conference. Many EU governments have traditionally been cautious in fully enforcing EU sanctions, and some of them have declined to publicly say whether they have frozen Russian assets.

Service members of pro-Russian troops remove branches covering a self-propelled howitzer 2S1 Gvozdika at their combat positions in the Luhansk region. Ecumenical Patriarch Bartholomew, the spiritual head of million Orthodox Christians worldwide, has attacked the support of the Russian Orthodox Church for Russia's military campaign in Ukraine. The Russian church disappointed us. I do not know how he can justify himself in his conscience," he said.

About million Orthodox Christians are in Russia. Ukraine has about 30 million Orthodox believers. Ukrainian MP Yevheniia Kravchuk said time is in short supply to transport 22 million tonnes of grain out of Ukraine ahead of the new harvest as Russia continues to blockade the country's Black Sea ports. Warnings of a global food crisis are growing as Russia and Ukraine together account for nearly a third of global wheat supplies, while Ukraine is also a major exporter of corn, barley, sunflower oil and rapeseed oil.

European Commission chief Ursula von der Leyen has called for talks with Moscow on unlocking wheat exports trapped in Ukraine as a result of a Russian sea blockade. Ukraine is expecting the new harvest to amount to some 70 percent of last year's crop as some of the fields are now under Russian control or have been mined, Kravchuk said.

Kravchuk called for help in demining fields and for fuel support as farmers needed diesel for their tractors and Ukraine had lost much of its refining capacity due to Russian attacks. Russian President Vladimir Putin has signed a decree simplifying the procedure for granting Russian citizenship to residents of the Kherson and Zaporozhye regions of Ukraine, according to a document published Wednesday on Russia's official legal information portal pravo.

The European Commission said in a statement on Wednesday that it wants to make violating EU sanctions a crime in the bloc, and is also proposing new measures that would make it easier for member states to confiscate and freeze assets of sanctioned Russian individuals and entities. Later on Wednesday, Russian Foreign Ministry spokesperson Maria Zakharova said five foreign ships were able to leave Mariupol port after being "cleared by Russian sappers.

Chairman of the Russian State Duma Vyacheslav Volodin said via Telegram on Wednesday that Russia will pay its external debt in rubles and all the necessary funds for payments are available, after the U. Treasury Department announced on Tuesday it would not renew a license to service Russia's external debt. Russia is ready to discuss providing humanitarian passage for vessels carrying food leaving Ukraine, Interfax news agency quoted Russian Deputy Foreign Minister Andrei Rudenko as saying on Wednesday.

Ukrainian President Volodymyr Zelenskyy said on Wednesday that he was only willing to speak directly with Vladimir Putin and not through mediators. He added that if the Russian president "understands reality" there was the possibility of finding a diplomatic way out of the conflict. Zelenskyy, speaking to an audience at the World Economic Forum in Davos, also said that Ukraine would fight until it recovered all of its territory. Earlier on Tuesday, Zelenskyy said in an interview with the Japanese public broadcaster NHK that Ukraine will resume talks with Russia when Russian troops get withdrawn to the positions held before February 24, which Russian Deputy Foreign Minister Andrey Rudenko called "not constructive" in response on Wednesday.

Von der Leyen told Politico in an interview that she didn't want to raise "false expectations" of a deal being stuck next week. Hungarian Prime Minister Viktor Orban declared a state of emergency immediately after his new government was sworn in on Tuesday. The special legal order takes effect at midnight on May Russia said the demining of the port of Mariupol was completed, Russian media reported on Tuesday, citing the defense ministry.

Russia said earlier this week that it had captured the southeastern Ukrainian city after a three-month siege. The United Arab Emirates has started shipping crude oil toward Europe for the first time since May , Bloomberg reported on Tuesday. The European countries have been seeking to diversify from Russian energy sources in the wake of the conflict in Ukraine. Russia's foreign ministry has imposed sanctions against British lawmakers who were directly involved in planning sanctions against Moscow, TASS reported Tuesday.

Stoltenberg told business and political leaders gathered in Davos that Putin "wanted less NATO on his borders and launched a war. Now he's getting more NATO on his borders and more members. The NATO chief said he was confident that the military bloc would be able "to welcome Finland and Sweden to our alliance. The Turkish government has so far opposed the pair's admission, citing their alleged support for autonomy-seeking Kurdish militants.

Mariupol's last stand. What is monkeypox? Turkish President Tayyip Erdogan spoke with Stoltenberg on Saturday, telling him that Ankara would not look positively on the two countries' bids unless they clearly show cooperation in the fight against terrorism and other issues.

This will happen tomorrow Wednesday , so the dialogue is continuing. Erdogan held phone calls with the leaders of the two Nordic countries on Saturday and discussed his concerns. Erdogan told Swedish Prime Minister Magdalena Andersson on Saturday that Ankara expected concrete steps to address its concerns, according to the Turkish presidency. He also said an arms exports embargo imposed on Turkey after its Syria incursion in should be lifted.

Ukraine is top of the agenda for the WEF, a four-day meeting of global business leaders, which began on Monday with a video address by Ukrainian President Volodymyr Zelenskyy. Aside from the Ukraine crisis, the post-pandemic recovery, tackling climate change, the future of work, accelerating stakeholder capitalism and harnessing new technologies are among the topics being discussed at Davos.

Secretary of State Antony Blinken discussed ongoing diplomatic efforts to seek a solution to the Russia-Ukraine conflict, with Ukrainian Foreign Minister Dmytro Kuleba in a phone call on Tuesday, the State Department said in a statement. Ukrainian soldiers who surrendered at the Azovstal steelworks are driven away by the Russian military — and the increase in prisoners requires an increase in guards.

Residents of the Russian-recognized People's Republic of Donetsk have been receiving text messages offering them work as prison guards to oversee the large number of Ukrainian soldiers captured in nearby fighting. The messages from the region's justice department were received and verified by CGTN reporter Aljosa Milenkovic while he was reporting from the area. They offer "a good salary and full social benefits" and encourage recipients to call for more information. A plea from Volnovaka.

EU vows to replace Russian fuel. It's not clear how many prisoners each side has taken but hundreds of fighters, many of them wounded, were transferred to pro-Russian areas in eastern Ukraine after surrendering following months of fighting at the Azovstal steelworks in Mariupol last week.

The economy of the two regions of Luhansk and Donetsk, which broke away from Kyiv in following the fall of Ukraine's pro-Russian government suffered as links with the rest of the country were severed. Years of fighting have also harmed the manufacturing heartlands in the predominantly Russian-speaking area. Moscow has said its primary objective in this phase of the conflict is to secure control of the Donbas region, with Ukraine acknowledging that up to of its troops are dying every day defending the parts it still holds.

Coffee chain Starbucks is to close all its coffee shops in Russia after 15 years in the country due to the military operation in Ukraine. The decision comes shortly after burger chain McDonald's decided to quit Russia. There are now almost 1, companies globally that have taken a stance since the start of fighting in Ukraine and curtailed their operations to some degree, according to a tracker list maintained by the Yale School of Management. Starbucks had suspended its operations in early March but on Monday said that it will "exit" Russia and "no longer have a brand presence in the market.

The company added: "We will continue to support the nearly 2, green apron partners in Russia, including pay for six months and assistance for partners to transition to new opportunities outside of Starbucks. Shelling of Ukrainian cities has cost thousands of lives and led to a humanitarian crisis.

Starbucks initially saw Russia as an important market to develop. In a December investor event, executives highlighted the country as a key emerging market for the brand, along with China, Brazil and India. Last week brought the departure of McDonald's, which had a bigger presence in Russia that dated back to the period near the end of the Cold War. But Starbucks' ceasing of operations is different to that by McDonald's, which said last Thursday it had reached a deal to sell to Russian businessman Alexander Govor, a McDonald's licensee.

The company will be rebranded under a new name but will retain its trademarks. France's Renault is selling its majority stake in Russia's biggest carmaker but with an option to buy back the stake. Yale School of Management produced its list to encourage and put pressure on companies to withdraw from Russia. When it was first published the week of February 28, only several dozen companies had announced their departure.

European Commission chief Ursula von der Leyen being interviewed in Davos. Orban said his cabinet needed room to manoeuver to respond to challenges quickly. South Africa abstained in March from a U. The court upheld his nine-year sentence. It said that Ukraine could harvest Ruble has reached four-year highs against the U. Speaking in Davos, European Commission chief Ursula von der Leyen called on Russia to end its sea blockade that has trapped wheat exports in Ukraine, putting a serious strain on world food supplies.

Von der Leyen, president of the European Union's executive, said a food crisis was approaching at full speed and some sort of dialogue with Moscow was needed to unlock 20 million tonnes of wheat stuck in Ukraine. Russia and Ukraine together account for nearly a third of global wheat supplies, while Ukraine is also a major exporter of corn, barley, sunflower oil and rapeseed oil.

Von der Leyen said the European Union should also step up its own production, making it easier for farmers to have a second crop or to increase wheat production. The ruble has strengthened about 30 percent against the dollar this year despite a full-scale economic crisis in Russia, making it the world's best-performing currency. Russia's currency is steered by capital controls imposed in late February to shield Russia's financial sector after Moscow's decision to send tens of thousands of troops into Ukraine prompted unprecedented Western sanctions.

Its strength has raised concerns about the negative impact on Russia's budget revenue from exports. On Monday, Russia cut the proportion of foreign currency revenue that exporters must convert into rubles to 50 percent from 80 percent. The rouble was 0. It may return to levels of against the dollar in June, Sinara Investment Bank said in a note.

Germany's economy minister said the European Union will likely agree an embargo on Russian oil imports "within days," Germany's economy minister said on Monday. Habeck warned, however, that an embargo would not automatically weaken the Kremlin. Rising global oil prices after the United States announced an embargo on Russian oil enabled it to rake in more income while selling lower volumes.

Therefore, the European Commission and United States were working on a proposal to no longer pay "any price" for oil, but to cap global prices, he said. Chinese Foreign Ministry spokesperson Wang Wenbin reiterated that the country's relationship with Russia can "withstand the new test of changing international situation," and that it has maintained the right direction.

Wang made the remarks on Tuesday when asked to comment on a recent quote by Sergey Lavrov, Russian foreign minister, that Moscow looks to strengthen its economic ties with China "even faster" amid mounting sanctions coming from the West. Russia initiated a "special military operation" in Ukraine since late February, and in response, the Western nations have imposed unprecedented sanctions. It is not aimed at third parties and will not be influenced by the outside world," Wang said at a regular briefing.

China and Russia will continue to work to promote "genuine multilateralism," and oppose international hegemony, Wang added. Russian President Vladimir Putin on Tuesday stressed the importance of expanding transport corridors to "predictable and responsible" partners because some countries choose to "close themselves from Russia," TASS reported.

The president also signed a decree on reducing the share of the mandatory sale of foreign exchange earnings by exporters from 80 percent to 50 percent. The document is posted on the official internet portal of legal information, according to TASS. Russia would achieve its objectives in Ukraine without being constrained by deadlines, Russian Security Council secretary Nikolai Patrushev said Tuesday in an interview with the Argumenty i Fakty, a Russian newspaper.

It cannot be otherwise, because truth, including historical truth, is on our side," he said, adding "we are not chasing deadlines. This will happen tomorrow so the dialogue is continuing," Haavisto said during a panel discussion in Davos. We proposed over 10 billion euros in macro-financial assistance — the largest such package ever conceived by the EU for a third country," she said.

In the speech, the senior EU official also accused Russia of using hunger and grain to wield power and putting the whole international order into question. Last week, Russia's UN mission said the global food crisis started before Russia's operation in Ukraine and blamed Western countries for provoking the food crisis while failing to acknowledge their role. Russian gas producer Gazprom said it continues to supply gas to Europe through Ukraine via the Sudzha entry point, with volumes on Tuesday seen at An application to supply gas via the main Sokhranovka entry point was rejected by Ukraine, Gazprom said.

The dollar exchange rate on the Moscow Exchange fell below 57 rubles on Tuesday, the first time since March , trade data showed. Editor's note: Nikola Mikovic is a freelance journalist based in Serbia. He covers mostly Russian, Ukrainian and Belarusian foreign policy issues and writes for multiple web magazines.

The article reflects the author's opinions, and not necessarily those of CGTN. Belarus was actively participating in the first phase of Moscow's special military operation in Ukraine by allowing Russian troops to use Belarusian territory for their actions in the eastern European country. Minsk now seems to be preparing for Poland's potential involvement in the Russo-Ukrainian conflict. According to Belarusian President Alexander Lukashenko, countries of the world should unite and prevent the regional conflict in Europe from escalating into a full-scale world war.

The Belarusian leader also stressed that Ukrainians will eventually have to "ask Belarus to prevent the separation of their country. Such a statement came one day after Ukrainian President Volodymyr Zelenskyy announced a "historic" joint customs control with Warsaw.

Once the law is adopted, Poles would likely be able to be elected as state authorities in Ukraine, and the two countries' security forces are expected to be integrated. Such a scenario, according to Moscow, could have an impact on the future of Ukraine. Russia, just like Belarus, claims that Poland will not hesitate to seize lands in western Ukraine. At this point, however, any annexation by Poland of Ukrainian territories does not seem very probable. However, if the conflict in the Eastern European country continues to drag on — which is something that Lukashenko recently warned about — it is entirely possible that Polish, or troops of other neighboring NATO countries, will eventually enter western Ukraine.

Such a move would allow the Ukrainian army to freely redeploy its troops from the West of the country to the Donbas, as well as to southern parts of Ukraine, given that Polish or other NATO forces would secure its western flank. If, however, Russia turns a blind eye to Polish actions, the West will undoubtedly interpret it as a serious demonstration of Russian weakness and will likely continue deploying NATO troops to Ukraine.

Quite aware that such a scenario is not off the table, Lukashenko recently said that "under certain circumstances, Russia, Belarus and Ukraine might fight against Poland for preservation of Ukrainian territorial integrity. For Moscow, the Donbas and Crimea are not part of Ukraine, and the southern part of Ukraine has been effectively under Russian control for almost three months. Thus, there is no doubt that certain political forces in Warsaw would seek to annex Lviv, and some other regions of western Ukraine that were part of Poland until However, it is highly uncertain if the U.

Minsk, for its part, has already started preparing for a potential escalation. On May 10, Viktor Gulevich, Belarusian chief of general staff, accused Washington and its allies of building up military personnel on Belarusian borders, which is why the Russian ally deployed its air defense, artillery and missile units for drills in the west of the country. Ukrainian armed forces, on the other hand, have reportedly built a new line of defense along the nation's border with Belarus, which suggests that Kyiv is taking Gulevich and Lukashenko's statements very seriously.

Ever since the Ukraine conflict escalated, the Belarusian leader repeatedly vowed not to send troops to the eastern European country, and the Kremlin never publicly pressured Lukashenko to make such a radical move. However, closer military and political ties between Warsaw and Kyiv could force Moscow and Minsk to eventually change their strategy. If you want to contribute and have specific expertise, please contact us at opinions cgtn.

Russia on Monday said domestic exporting companies would have to sell 50 percent of their income in foreign currency, a reduction from 80 percent, after Moscow said the ruble had stabilized. After the West slapped sanctions on Russia over the start of Moscow's military offensive in Ukraine in February, financial authorities introduced harsh capital controls. They ordered exporting companies to sell 80 percent of their export earnings to buy rubles, among other measures.

Since then, the ruble has staged a spectacular rebound and strengthened around 30 percent against the dollar. On Monday, the finance ministry, citing a government commission, said exporting companies would now be required to sell 50 percent of their income in foreign currency. President Vladimir Putin has repeatedly claimed that Russia's economy has managed to weather the barrage of unprecedented Western sanctions. There is nothing else to talk about," Zelenskyy said.

Belarusian President Aleksandr Lukashenko has sent a message to UN Secretary General Antonio Guterres on the topic of European and international security amid the ongoing events in Ukraine, Belta news agency reported citing the press service of the Belarusian Ministry of Foreign Affairs. Starbucks said in a statement on Monday that it will cease operations after 15 years in Russia, shuttering its cafes in the country.

The coffee chain, which suspended its operations in early March following the Russia-Ukraine conflict, said it "has made the decision to exit and no longer have a brand presence in the market. The cafes to be closed, which are all licensed locations, account for less than 1 percent of the company's annual revenue, according to a CNBC report on Monday.

The move follows a similar action last week by the U. McDonald's had roughly restaurants in Russia, most of which were operated by the company instead of licensees, CNBC reported. The firm on Thursday announced that it would be selling those locations for an undisclosed sum to a Siberian franchisee to run under a new brand.

Secretary of Defense Lloyd Austin on Monday welcomed defense ministers of more than 40 countries in the second virtual meeting of the Ukraine Contact Group. The Russian ruble firmed more than 6 percent against the euro on Monday to a near seven-year high, boosted by capital controls, strong oil prices and an upcoming month-end tax period.

By p. GMT, the ruble had gained 6. It was 4. The international community should help secure safe passage for food export vessels in a corridor out of the port city of Odesa, the BBC quoted Ukrainian First Deputy Prime Minister Yulia Svyrydenko as saying on Monday. Hungary on Monday stuck to its demands for energy investment before it agrees to a Russian oil embargo. The European Commission proposed a new package of sanctions against Russia earlier this month but the measures have not yet been adopted.

Russia's transition to trade with other countries in rubles, including with Belarus, has strengthened the rubles, Putin told Lukashenko, according to TASS news agency. Russia's economy is withstanding sanctions, despite all the difficulties, he said. Lukashenko said the West's decisions to slap sanctions on Russia and Belarus hit themselves, according to RIA news agency. He expressed concerns that the West is "taking steps to dismember Ukraine.

Shishimarin, a year-old tank commander, had pleaded guilty to killing a year old man in the northeastern Ukrainian village of Chupakhivka on February There was no immediate response from Russia on the verdict. The Kremlin has previously said that it has no information about the trial and that the absence of a diplomatic mission in Ukraine limits its ability to provide assistance.

Russia decided to withdraw Moscow's candidacy for the right to host the World Expo, the foreign ministry said on Monday. It is hardly possible to talk about the possibility of exchanging Ukrainian politician Viktor Medvedchuk for Ukrainian soldiers who left Azovstal, Kremlin spokesperson Dmitry Peskov said on Monday, adding that they are completely different categories of people.

There should be no trade with Russia and the world needs to set a precedent, he said. Zelenskyy said he hopes that at Lugano conference in July all countries will come up with offers for reconstruction in Ukraine. Moscow is ready to return to the negotiating table with the constructive position of Kyiv, Russian Deputy Foreign Minister Andrei Rudenko said on Monday.

He added that Russia would not rule out the possibility of discussing with Kyiv the exchange of prisoners with Azovstal. Poland has decided to terminate an intergovernmental agreement with Russia regarding the Yamal gas pipeline, Polish Climate Minister Anna Moskwa said on Twitter on Monday. The European Union on Monday extended through its suspension of rules against overspending by the bloc's governments, prolonging a pandemic-era reprieve because of the conflict in Ukraine.

The article reflects the author's opinions and not necessarily those of CGTN. When U. With that reorientation, it officially became a 'surrogate' war of the U. While U. Many are still talking about the need for negotiations, including French President Emmanuel Macron. While there is yet only 'rumbling' underneath the surface, the full brunt of this momentous shift has yet to be felt. Biden's idea is that through economic warfare, combined with Ukrainian sacrifices on the battlefield, he can bring Russia down, or perhaps only President Vladimir Putin, whom he previously said should "no longer be in power.

This on top of the billions that have already been spent on this risky venture. The sanctions on Russia and the attempt to prevent the sale of Russian gas and oil to Europe have already led to a serious crisis for Europe's energy security. Data of the American adults' negative feelings on the U.

While Biden is already tapping America's strategic reserves to keep the price of gasoline in the U. More significantly, the price of food, which is heavily dependent on energy — and fertilizer — is now sky-rocketing. And business confidence is going down the tubes with Wall Street experiencing a virtual "market meltdown," not seen since the days of the crisis. Biden is also getting hit in his own numbers with the lowest figures of people believing that he is doing a good job since he became president.

He may not care since it is not likely that he will run for another term. The presidency takes its toll on everyone, and most tellingly on someone Biden's age. But his obsession with Ukraine seems to have made him oblivious to everything else. Certainly, he can continue his attempt to blame the economic downturn on Putin, but fewer and fewer people are going to accept that for long. He is the president and his job is to fix things. And as Americans continue to see billions of dollars flying off to somewhere in Eastern Europe, while U.

The Federal Reserve has already raised interest rates in the face of rising inflation and has cued in more to be made in the course of the year. But the calculations as to how this situation will develop could be radically overturned by reality, requiring much more than they have predicted. And the rising interest rates will undoubtedly lead to reduced investment and more unemployment.

The longer-term effects will be on the role of the dollar as a reserve currency. The arbitrary measures taken against Russia by freezing Russia's dollar assets have taken the luster off the dollar-based system. If the U. And the measures now taken by Russia and other countries still prepared to work with them economically and to purchase Russian oil and gas are leading to alternative financial frameworks which bypass the dollar.

All in all, we are just at the beginning of what threatens to become a major economic blowout for the U. Are the Europeans going to stay on board in a conflict in their neighborhood with a nuclear power as jobs are lost, and blackouts and brownouts occur due to energy shortages? And even if the political elites are prepared to weather the storm, are their citizens likewise ready to tighten their belts to preserve the so-called American way of life?

It is sure to be a hot summer in more ways than one as the effects of sanctions and war begin to take their toll on people's livelihood. And you may soon begin to see people take to the streets to demand change from what has become an absolutely unacceptable situation.

The Ukrainian lawmakers also banned medicine from Russia and Belarus, and canceled the agreement between Russia and Ukraine on the avoidance of double taxation, according to the report. Ukrainian President Volodymyr Zelenskyy on Sunday announced an agreement reached with Polish President Andrzej Duda to simplify border crossing between countries.

A bid by Ukraine to join the European Union could not be finalized for "15 or 20 years," France's Europe minister said Sunday. Serbian President Aleksandar Vucic has said he hopes to meet his Russian counterpart Vladimir Putin next week to discuss gas supplies, Sputnik reported on Sunday. Only Ukraine has the right to decide its future, Poland's president told lawmakers in Kyiv on Sunday, as he became the first foreign leader to give a speech in person to the Ukrainian parliament since the conflict began.

Mariupol's mayor Konstantin Ivashchenko Sunday said public transport had resumed in the city, and that four hospitals and three gas stations had also resumed operations, according to TASS. He is the first foreign head of state to address the council since the conflict began, according to the president's office.

Lithuania officially stopped importing Russian gas, oil and electricity on Sunday, according to the country's Ministry of Energy. Polish President Andrzej Duda is now in Ukraine and is expected to deliver an in-person address at the country's parliament on Sunday, making him the first head of a foreign state to do so since Russia's "special military operation" in Ukraine began on February 24, the Polish presidency said in a short statement on Saturday.

The U. Turkish President Recep Tayyip Erdogan urged Sweden to end financial and political support, as well as supply of weapons, to "terrorist organizations" during his phone talks with Swedish Prime Minister Magdalena Andersson on Saturday, Turkish media outlet Anadolu Agency reported. Finnish President Sauli Niinisto said on Saturday that "Finland condemns terrorism in all its forms and manifestations," after his phone call with Erdogan.

Niinisto tweeted that, "as NATO Allies, Finland and Turkey will commit to each other's security and our relationship will thus grow stronger, and close dialogue continues. The Foreign Ministry said that "Russia is not looking for confrontation and is open to honest dialogue, separating the American people from the U. Ukrainian Foreign Minister Dmytro Kuleba tweeted on Saturday that "Ukraine has established two alternative land routes to deliver food exports and save Africa and other regions from hunger.

Kuleba accused Russia of putting millions of people at risk of hunger by blocking Ukrainian ports and urged Russia "must end its blockade to allow full and free export. The Russian Defense Ministry said on Saturday that high-precision Kalibr missiles destroyed a large batch of weapons and equipment delivered to Ukraine from the U.

The "Ukraine war" can only be resolved through "diplomacy," Ukrainian President Volodymyr Zelenskyy said on Saturday amid a deadlock in negotiations between Kyiv and Moscow. Russia's Gazprom on Saturday halted fuel exports to neighboring Finland, the Finnish fuel system operator said. The prime minister's spokesperson said Johnson asked Erdogan to work with the Swedish, Finnish and NATO teams to address any concerns ahead of a leaders summit in Madrid, Spain, next month, confirming that Britain stands ready to support.

Johnson and Erdogan also agreed to work to unlock supply routes for Ukrainian grain to alleviate rising global food prices. The Russian Defense Ministry said on Friday that it has taken full control of the Azovstal steel plant in the southern Ukrainian city of Mariupol. Ukrainian President Volodymyr Zelenskyy said on Friday that all civilians who were trapped at the plant have been evacuated, adding that he believes the evacuation of all Ukrainian defenders will be completed in the near future.

During the meeting, Zelenskyy called for international pressure on Russia, saying the key to this is now the introduction of the sixth package of EU sanctions against Russia. Canada has imposed additional sanctions against 14 Russian individuals, including several Russian businessmen and their families, according to a statement from Canadian Foreign Ministry. Canada will provide a new loan of million Canadian dollars to Ukraine as financial assistance, Canadian Deputy Prime Minister Chrystia Freeland announced on Friday.

Russian President Vladimir Putin on Friday said that the number of cyber attacks on Russia by foreign "state structures" had increased and Moscow would need to bolster its cyber defences. The Russian president proposed the creation of state information security system and other means limiting foreign software and hardware systems. Let me remind you that before that, 1, marines laid down their arms there," the minister said at a military board meeting.

He added that civilians, including 47 children, were rescued from the Azovstal area in Mariupol. He warned that the entry of Finland and Sweden into NATO would continue to fuel tensions in the region, especially given the fact that U.

She added that EU had proposed an additional 9 billion euros in loans for Ukraine this year. UN Secretary-General Antonio Guterres on Thursday called for efforts to reintegrate the agricultural production of both Russia and Ukraine into world markets. Investing in political solutions to end conflicts, preventing new ones, and building sustainable peace is crucial in addressing food insecurity, said the secretary-general.

Furthermore, he called for attention to the interconnected risks of food insecurity, energy, and financing, which "require far greater coordination and leadership. Serhiy Haidai, governor of Ukraine's Luhansk region, said on Friday that 13 civilians were killed by Russian shelling in the region overnight. State Department spokesperson Ned Price. It was the first conversation between the generals since Russia began its "special military operation" in Ukraine on February The new defense package includes 18 additional howitzers, 18 more tactical vehicles and three additional counter-artillery radars, Pentagon spokesperson John Kirby said during a news briefing.

The Senate voted in favor of the emergency package of military, economic and humanitarian assistance, by far the largest U. French President Emmanuel Macron said on Thursday that he wanted the European Union to give a "quick opinion" on Moldova's request for membership of the bloc, as he hosted a meeting with Moldovan President Maia Sandu in Paris. Macron added that the risk of the conflict between Ukraine and Russia spreading to neighboring countries could not be ruled out.

The Russian Foreign Ministry announced on Thursday that it had expelled four Slovenian diplomats in a retaliatory move. British Prime Minister Boris Johnson and Ukrainian President Volodymyr Zelenskyy on Thursday discussed longer-term security proposals for Ukraine and ways to get grain exports out of the country, Johnson's office said. The European Parliament has called for sanctions to be imposed on former German chancellor Gerhard Schroeder for his business and political ties to Russia.

The European Union legislature passed a resolution on Thursday that said sanctions against Russia should be extended "to the European members of the boards of major Russian companies and to politicians who continue to receive Russian money. Germany on Thursday removed official perks accorded to the former chancellor, assessing that he has failed to uphold the obligations of his office by refusing to sever ties with Russian energy giants.

A Ukrainian general said on Thursday the "evacuation" of Ukrainian troops from the city of Mariupol was continuing but provided no details. Civilians must be protected," he tweeted. Russia on Thursday expelled five diplomats of the Portuguese embassy as a response to Portugal's expulsion of 10 Russian diplomats in April. Ukraine's foreign minister Dmytro Kuleba criticized the "second-class treatment" of Kyiv by some EU countries on Thursday, after German Chancellor Olaf Scholz said the war-torn country's bid to join the bloc cannot be sped up.

Italian Prime Minister Mario Draghi said on Thursday to the Senate that government estimates indicate that the country could become independent from Russian gas in the second half of , Italy's biggest news agency ANSA has reported. Ukraine's bid to join the EU cannot be sped up despite the current crisis, German Chancellor Olaf Scholz said on Thursday, adding that the bloc must find a 'fast and pragmatic' way to help Kyiv.

The Russian Defense Ministry said on Thursday that Ukrainian fighters from the Azovstal steelworks in Mariupol have surrendered in the last 24 hours, adding that a total of 1, people, including 80 wounded, had given themselves up so far.

The United States, Canada and Switzerland are among the top three unfriendly countries that have imposed the most sanctions against Russia, and provoked a global rise in energy and food prices, Russian State Duma Speaker Vyacheslav Volodin said on Thursday, according to TASS news agency. The administration now plans to push for her quick confirmation by the full Senate.

State Department officially reopened its embassy in Kyiv on Wednesday after closing it for three months. Secretary of State Antony Blinken said at the United Nations during a ministerial meeting on global food security on Wednesday. Blinken also said that the U. Ukrainian President Volodymyr Zelenskyy on Wednesday signed a presidential decree to extend martial law and mobilization in Ukraine for another 90 days. Russia's foreign ministry said on Wednesday that it had expelled 27 Spanish diplomats in response to Spain earlier expelling Russian diplomats.

EU leaders have agreed to set up a platform for the joint purchase of gas, liquefied natural gas LNG and hydrogen, European Commission President Ursula von der Leyen said during a press conference in Brussels on Wednesday. About 10 billion euros will fund missing links for gas, LNG and oil infrastructure to stop shipments from Russia, she said. Turkish President Recep Tayyip Erdogan, who has threatened to block Finland and Sweden from joining NATO, on Wednesday urged the alliance's members to "respect" Ankara's concerns regarding the two countries, which Turkey accuses of providing safe haven to terrorists.

Russia on Wednesday expelled 34 French diplomats in response to the expulsion of 41 Russian diplomatic employees from France in April, the country's foreign ministry said. Kremlin spokesman Dmitry Peskov said on Wednesday that Ukraine had shown a "complete unwillingness" to continue negotiations on a peace deal. On Tuesday, Ukrainian negotiator Mykhailo Podolyak issued a statement saying peace talks were "on hold.

Peskov added that Azovstal fighters must lay down their arms and surrender if they wanted to exit the steel plant in Mariupol. Denis Pushilin, leader of the self-proclaimed Donetsk People's Republic, said that a court would decide the fate of the Ukrainian fighters who had "surrendered" at the Azovstal steel plant in Mariupol, a local media outlet reported on Wednesday.

Russia said earlier that a total of Ukrainian fighters, including 80 wounded, had surrendered from the bunkers and tunnels below the Azovstal steelworks since Monday. The main commanders inside the plant had yet to surrender, DAN news agency quoted Pushilin as saying. Although Russia and Ukraine have conducted several prisoner exchanges, it is unclear how these surrenders will be treated. The Kremlin has guaranteed that all would be treated "in accordance with international standards," but Russia's lower house of parliament, the State Duma, is considering to ban the exchange of Russian servicemen for members of Ukraine's ultra-nationalist Azov regiment, which made up a large part of the fighters defending Mariupol.

In April, the Spanish and French authorities expelled a number of employees from the Russian diplomatic missions in their respective countries. The Russian Defense Ministry said on Wednesday that Ukrainian fighters trapped at the Azovstal steel plant in Mariupol had "surrendered" in one day, including 29 wounded. It also said that fighters had "surrendered" at the Azovstal plant in total, including 80 wounded, of which 51 who needed inpatient treatment were transferred to the Novoazovsk hospital in Donetsk.

Sweden and Finland on Wednesday submitted simultaneous membership applications to the North Atlantic Treaty Organization NATO , shifting both countries' long-held neutral stance and reflecting one of the most significant changes in Europe's security architecture for decades. You are our closest partners, and your membership in NATO will increase our shared security," Stoltenberg said. With the applications formally submitted, the Nordic countries and their many backers now face uncertain months where any resistance to their bids needs to be overcome, with all 30 of NATO's members needing to approve the enlargement.

Turkey, which has strained relations with its NATO allies in recent years, has voiced objection to the applications. President Recep Tayyip Erdogan has accused Helsinki and Stockholm of harboring militants from the Kurdistan Workers' Party PKK , which has waged a decades-long insurgency against the Turkish state and is deemed a terrorist group by Ankara. Buses with service members of Ukrainian forces from the besieged Azovstal steel plant who have surrendered aboard drive away under escort of the Russian troops in Donetsk, May 17, Ukraine will not exchange its territories for a peace deal with Russia, the government-run Ukrinform news agency reported on Tuesday, citing Mykhailo Podolyak, a member of the Ukrainian delegation to the peace talks with Russia.

He noted that many Ukrainian civilians were either killed or assaulted in the conflict, making it impossible for Ukraine to make concessions to Russia. Ukraine will not agree on a ceasefire with Russia without troop withdrawal as Russia will control part of Ukrainian territory, Podolyak said. He also ruled out the signing of a deal with Russia similar to the Minsk peace agreements, saying it would only lead to a frozen conflict, but not sustainable peace.

Earlier in the day, Podolyak said that the negotiation process within the delegations between Ukraine and Russia has been suspended. At the same time, he voiced the belief that peace talks will resume. Ukraine and Russia held the latest round of their face-to-face peace talks in Istanbul, Turkey, on March The Minsk agreements, reached in September and February respectively, outlined the steps needed to end the conflict in Ukraine's eastern region of Donbas that started in April Ukraine has surpassed Egypt and Israel as the largest recipient of U.

The report states that the U. The European Commission will unveil a billion-euro plan on Wednesday that will detail how Europe can "end its reliance on Russian fossil fuels" by , thus pivoting from Moscow toward green energy, Reuters has reported. Russia currently supplies 40 percent of the bloc's gas and 27 percent of its imported oil, and EU countries are struggling to agree on sanctioning the latter.

The Australian government on Wednesday announced further sanctions against more than two dozen individuals and entities in the media industry, political and security areas over the Ukraine conflict. The targets include the first deputy chief of the general staff of Russia's Armed Forces, the first deputy director of the Federal Security Service, Russian journalists and news anchors, acting ministers and a museum curator, as well as pro-Russia research and cultural institutions.

Canada introduced a bill in the Senate on Tuesday that would ban Russian President Vladimir Putin and some 1, other members of his government and military from entering the country. Canada said the decision was "one of the many ways in which we're holding Russia accountable for its crimes," referring to the "special military operation" Moscow launched against Ukraine in February. However, seemingly being protected by NATO, the members have already lost their strategic autonomy at large, becoming tools for the U.

A senior Russian official on Tuesday has accused the U. But Mykhailo Podolyak, a member of the Ukrainian delegation, voiced his belief that peace talks "will resume. The most recent round of face-to-face talks between Russia and Ukraine took place in Istanbul on March A Ukrainian police officer documents the destruction at what was previously one of Europe's largest clothing markets "Barabashovo" in Kharkiv on May 16, French President Emmanuel Macron told his Ukrainian counterpart Volodymyr Zelenskyy during a call on Tuesday that arms supplies from Paris would "increase in intensity", according to a statement from the French presidency.

Ukrainian President Volodymyr Zelenskyy said on Tuesday he had a "long and meaningful" phone conversation with Macron about the latest situation in Ukraine. Raised the issue of fuel supply to Ukraine," Zelensky said on Twitter. Held a substantive discussion of our application for the status of a candidate for EU membership," Zelensky tweeted. Their applications will culminate decades of military non-alignment to join the alliance as a defense mechanism.

But the main obstacle to their membership comes from within the alliance despite NATO Secretary General Jens Stoltenberg repeatedly insisting the two countries would be welcomed "with open arms". Turkey has insisted that Ankara will not approve expansion. Any membership bid must be unanimously approved by NATO's 30 members. Niinisto said Tuesday he was "optimistic" Finland and Sweden would be able to secure Turkey's support.

Andersson and Niinisto are to meet U. President Joe Biden in Washington Thursday to discuss their historic bids. After a marathon debate lasting a day-and-a-half, out of Finnish lawmakers voted in favour of NATO membership, a dramatic reversal of Finland's military non-alignment policy dating back more than 75 years. Finland will proceed with its application for North Atlantic Treaty Organization NATO membership, a special parliament session held on Tuesday confirmed, marking a historic policy shift prompted by the ongoing Ukraine crisis.

After a marathon debate lasting a day and a half, of members of parliament voted in favor of NATO membership, a dramatic turnaround from Finland's military non-alignment policy. Sharing a 1,kilometer mile border with Russia, the country has in the past stayed out of military alliances. At the start of the debate, Prime Minister Sanna Marin told parliament the country's security environment "has fundamentally changed. Indeed, the synthesis of 1 from 1,4,5,8-substituted naphthalene 5 , [2.

Several approaches to construct naphthalenetetracarboxylic diimide 4 as a main precursor of 2,7-diazapyrene are reported starting from 1,5-dichloro-8 ref. The authors also developed another straightforward approach by using selenium as an oxidant. Later, various researchers followed this same procedure to synthesize this moiety by modifying few conditions Scheme 3. Several examples of the synthesis of 2,7-diazapyrene core 1 from the commercially available precursor, 1,4,5,8-naphthalenetetracarboxylic anhydride 3 , were presented in the literature.

Sotiriou-Leventis and co-workers 40 developed an alternative and convenient approach via very fast, low-priced, and high yielded synthesis of 2,7-diazapyrene. The last step involves the oxidation of 19 by 2,3-dichloro-5,6-dicyano-1,4-benzoquinone DDQ in anhydrous MeCN at room temperature followed by the addition of concentrated acid to obtain the corresponding diazapyrenium salt 16a—d. In , Aksenov et al. Kamata and Wasada 44 reported synthesis of 2,7-diazapyrene 1 from 1,4,5,8-tetrakis bromomethyl naphthalene 21 according to the Scheme 8 , involving the cyclization, carboxylation, hydrolysis and oxidative aromatization.

The disadvantage of the method is the low availability of starting substrates. In , Miyake et al. Later, the same group provided another approach to afford DAP derivatives bearing various alkyl substituents at 1,3,6,8 positions 27a—c. It was then subject to reductive aromatization, followed by alkylation of the latter through Ni-catalyzed cross-coupling with alkyl Grignard reagents Scheme Very recently Sundermeyer and co-authors 47 reported facile reductive O -triflylation and O -silylation of naphthalene diimide 14a.

The resulting highly reactive 1,3,6,8-tetratriflato-2,7-diazapyrene was served as a versatile platform for further functionalizations via Sonogashira cross coupling or nucleophilic aromatic substitution by piperidine. It is worthy to mention that quite similar approach was reported earlier for 2,9-diazaperylens.

The X-ray diffraction analysis of 36a 0 revealed a quinoidal structure. The 1 H NMR chemical shift of the proton on the diazapyrene core of 36b 0 was shifted upfield relative to that of the corresponding aromatic diazapyrene 24a. Theoretical calculations clearly supported the presence of an anticlockwise paratropic ring current.

The fluorescence lifetime of azapyrenes, measured in a diluted solution 1. A significant change in the photophysical properties of 25 was caused by the use of protic solvents. Experiments were carried out on the protonation of trifluoroacetic acid 25 in CH 2 Cl 2 , which led to the appearance of a new absorption band at nm and the emission spectrum was bathochromically shifted Fig. The lifetime measured in dilute solution 1.

Based on these results, the new emission at nm was assigned to the excimer emission. In addition, the electrochemical properties of diazapyrene 25 and 1,3,6,8-tetrapentylpyrene were examined by cyclic voltammetry CV. The experimentally confirmed low LUMO level motivated the authors to evaluate the electron mobility of 25 in the hope to find a new n -type semiconducting material. The authors suggested that these changes in the optical properties resulted from not only the electric modulation due to the quaternization of the nitrogen atoms but also from the suppression of the rotational dynamics of the peripheral aryl groups due to the steric repulsion between methyl groups on the nitrogen atoms and the aryl groups.

Absorption and emission spectra of 1,3,6,8-tetratriflato-2,7-diazapyrene 29 , 1,3,6,8-tetraalkynyl-2,7-diazapyrene derivatives 30a,b , 1,3,6,8-tetraamino-2,7-diazapyrene 31 and tert -butyl-dimethylsilyl ether 28c as analogues of Miyake's tetraaryl-2,7-diazapyrene derivatives 24a—d , 25 were recorded in DCM Fig.

This is different from Miyake's derivatives displaying four aryl substituents preferentially in a nonconjugated conformation with respect to the central plane. According to the authors, these 2,7-azapyrenes can be classified as electron mediators, both electron donors and acceptors.

Azapyrenes 30a and 30b show a higher first oxidation potential in comparison to silyl ethers 28a—c. This is characteristic of the energetic stabilization of the LUMO of alkynes 30a and 30b in comparison to silyl ethers. The reaction of demethylation of compound 37 to 1,3,6,8-tetra 2-hydroxyphenyl -2,7-diazapyrene 38 using pyridine hydrochloride was performed.

In the case of the reaction of 38 with 8 equiv. The broad absorption bands of 39a anti - and 39b syn - from to nm were bathochromically shifted relative to 1,3,6,8-tetra 4- tert -butylphenyl -2,7-diazapyrene 24a as comparison compound in CH 2 Cl 2 due to the boron complexation.

The donor—acceptor interaction in these supramolecular complexes could also be readily distinguished by the characteristic color changing of the solution. For instance, the intercalation of 2,7-diazapyrenes with DNA 54—56 and some of its mononucleotides 57 were reported. Obviously, such interactions between DAP derivatives and nucleic acids can be responsible for producing a multitude of potentially advantageous biological activities, including antiproliferative and antitumour ones, as well as antibacterial, antiviral and antiprotozoal effects.

All these activities were discussed in detail in the recent review by Zhirov et al. Stang's group performed interaction of a variety of bidentate ligands bipyridine, diazapyrene, dicyanobenzene, and dicyanobiphenyl with square-planar cis -bis phosphine Pt and bis triflate Pd complexes resulting in molecular squares in high yields via self-assembly. Complex representing linear, coplanar ribbons of ligands has been synthesized for studying the influence of anions and intermolecular aromatic interactions on the orientation.

Later, complexation of DAP-derived guests of diverse structures including dendronised ones 77,78 was also explored with regard to other hosts, such as molecular clips, 77 pillar[7]arenes, 79 and cucurbiturils. Furthermore, 2,7-diazapyrene derivatives are successfully used for the assembly of pseudorotaxane-type molecular machines, 82—85 which can be driven, for instance, by action of light 82 or by chemical means.

Besides, the latter research team exploited DAP scaffolds in the design of catenane-type molecular machines. As a result, both [2]catenanes 86,87 and [3]catenanes 72 were afforded. Meanwhile, Stoddart et al. These structures are expected to serve as prototypes in the development of high-density data memories. It is noteworthy that some of the works discussed above 80,81 intertwine also with another scope of DAP derivatives application, namely the sensing ability of the latter.

In the following subsection, we mention a few more examples related to this topic. Later, Chang et al. Furthermore, Balkus Jr. Finally, Coskun et al. In summary, the application range of DAP derivatives appears to be very broad, which is mostly based on remarkable photophysical and binding properties of 2,7-diazapyrene unit. Of course, these features are expected to be the cornerstone for the further developments as well.

Obviously, new relevant research focused on employing DAP derivatives in various fields of science won't be long in coming. In addition to electronic properties the nature of substituents dramatically affected the packing structures of tetra-substituted 2,7-diazapyrenes in the solid state.

Compare to tetrasubstituted pyrenes the replacement of the C—H moieties with nitrogen atoms at the 2 and 7 positions in 2,7-diazapyrene reduces the steric repulsion between the central core and the peripheral aryl groups. Thus, 2,7-diazapyrene-based chiral MOF thin films were shown 75 to have strong circularly polarized luminescence CPL properties, and 2,7-diazapyrenium-based ligand and square-planar Pd II or Pt II complexes were found 71 to recognize polycyclic aromatic hydrocarbons PAHs.

In medicinal applications, 2,7- as well as other azapyrenes were successfully used to recognize nucleic acids and bind to specific areas of DNA, major or minor grooves, or integrate between DNA bases arranged in specific nucleotide sequences. Dispirit unique electronic and supramolecular properties the photophysical studies of 2,7-diazapyrenes so far reported only in very few publications, which might be due to the limited synthetic approaches towards these azaheterocycles.

So far, the most common methods involve reductive aromatization of naphthalene diimides, obtained either from naphthalene-1,4,5,8-tetracarboxylic acid or its anhydride, 37,39—41,69 with the following transition metal TM -catalyzed coupling reactions with aryl-boronic acids, 45 Grignard reagents 46 or acetylenes. As a consequence, this review enables one to stimulate research in this fascinating area of organic synthesis and supramolecular chemistry.

So, we believe that this updated account of developments will be of much utility in organic synthesis, the pharmaceutical industry, and material science. DOI: Received 13th January , Accepted 1st March Abstract 2,7-Diazapyrenes are promising azaaromatic scaffolds with a unique structural geometry and supramolecular properties. Reproduced be the permission of ref. KGaA, Weinheim. Scheme 1 Four main routes to construct of 2,7-diazapyrene derivatives.

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Alexey gromov forex reviews Alexander Denisov, a round of applause! Andersson and Niinisto are to meet U. Putin signed a decree affecting residents of the southern region of Kherson, which is under the full control of Russian troops, and the southeastern region of Zaporizhzhia, partially controlled by Moscow. After that, an analyst named Igor contacted me, he helped me to understand the Platform, explained the strategy. But he is right, trading without stops is the way to the downside. Indeed, the synthesis of 1 from 1,4,5,8-substituted naphthalene 5[2.
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